3M Canada Company 1840 Oxford Street East, Post Office Box 5757 London, Ontario N6A 4T1 Medical Emergency Telephone: (519) 451-2500, Ext. 2222 Transportation Emergency Telephone (CANUTEC): (613) 996-6666 ======================================================================= Material Safety Data Sheet ======================================================================= Document id : 26-6626-1 Issue date : 2009/11/24 Version : 2.00 Supersedes date : 2009/06/19 Copyright, 1997, 3M Canada Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Prepared by: Corporate Regulatory Services, 3M Canada Company Telephone: (800) 364-3577, Fax: (800) 603-7758, Web Site: www.3M.ca ----------------------------------------------------------------------- 1 Chemical Product and Company Identification ----------------------------------------------------------------------- Tradename: Skin Antiseptics (2.0% CHG) Product ID: CH-0000-1561-0 CH-0000-1564-4 Intended Use of Product: Sanitizer Division: ZD - 3M Canada Company ----------------------------------------------------------------------- 2 Hazards Identification ----------------------------------------------------------------------- Critical Hazards: No data available. See Sections 7 and 11 for further information. ----------------------------------------------------------------------- 3 Composition/Information on Ingredients ----------------------------------------------------------------------- Ingredient Name CAS Number Percentage ------------------------------------- ------------------ ------------- WATER 7732-18-5 90 - 100 CHLORHEXIDINE DIGLUCONATE 18472-51-0   2 Ingredient Statements: Some of the formats of this product as part of their composition Skin Antiseptics (2.0% CHG) Page 2 of 7   ----------------------------------------------------------------------- would include either a swab or swab stick as part of their delivery systems. NOTE: Each percentage is expressed as the ratio of the weight of the ingredient to the weight of the controlled product. ----------------------------------------------------------------------- 4 First Aid Measures ----------------------------------------------------------------------- Instructions for Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Instructions for Skin Contact: Remove contaminated clothing and shoes. Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Wash contaminated clothing and clean shoes before reuse. Instructions for Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. Instructions for Ingestion: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. ----------------------------------------------------------------------- 5 Fire Fighting Measures ----------------------------------------------------------------------- Flash point: Not applicable Lower Explosive Limit (%): Not applicable Upper Explosive Limit (%): Not applicable Autoignition temperature: Not Available Suitable Extinguishing Media: Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). Exposure Hazards during Fire: No data available. Combustion Products from Fire: Carbon dioxide - During Combustion; Hydrogen Chloride - During Combustion; Ammonia - During Combustion; Oxides of Nitrogen - During Combustion; Unusual Fire and Explosion Hazards None known. Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Cool fire exposed containers with water spray. Special Instructions: Not applicable. Skin Antiseptics (2.0% CHG) Page 3 of 7   ----------------------------------------------------------------------- ----------------------------------------------------------------------- 6 Accidental Release Measures ----------------------------------------------------------------------- Personal Precautions: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Environmental Procedures No data available. Methods for cleaning up No data available. Spill Response: Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with water. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. ----------------------------------------------------------------------- 7 Handling and Storage ----------------------------------------------------------------------- Storage Requirements: No data available. Incompatible Materials: Store away from heat; Sparks and/or Flames; Store out of direct sunlight. Ventilation: No data available. Use Instructions: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. For industrial or professional use only. Skin Antiseptics (2.0% CHG) Page 4 of 7   ----------------------------------------------------------------------- ----------------------------------------------------------------------- 8 Exposure Controls/Personal Protection ----------------------------------------------------------------------- Personal Protection ------------------- Eye Protection: Avoid eye contact with vapours, mists, or spray. Hand Protection: Not applicable. Skin Protection: No data available. Respiratory Protection: Avoid breathing of vapours, mists or spray. Ingestion (Prevention): Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Recommended Ventilation: Use in a well-ventilated area. Ingredient Exposure Data ------------------------ WATER (7732-18-5) LD50 (rat, oral) > 90 ml/kg LC50 (rat, inhalation/4 hours) No data available. Exposure Limits No data available. CHLORHEXIDINE DIGLUCONATE (18472-51-0) LD50 (rat, oral) No data available. LC50 (rat, inhalation/4 hours) No data available. Exposure Limits No data available. ----------------------------------------------------------------------- 9 Physical and Chemical Properties ----------------------------------------------------------------------- Physical form,Color,Odour: Liquid; Clear; Odourless; Odour Threshold: No data available. pH: Not Available Boiling point/boiling range: 99 C Melting point/melting range: Not applicable Vapour pressure: Not applicable Water Solubility: Complete Specific gravity: 1.01 Water=1 Vapour density: Not applicable Volatile organic compounds: Not Available Evaporation rate: 1 Water=1 Viscosity: Not Available Percent Volatile: Not Available Skin Antiseptics (2.0% CHG) Page 5 of 7   ----------------------------------------------------------------------- ----------------------------------------------------------------------- 10 Stability and Reactivity ----------------------------------------------------------------------- Conditions to Avoid: Store away from heat; Sparks and/or Flames; Store out of direct sunlight. Materials to Avoid: None known. Hazardous Decomposition: Carbon dioxide - During Combustion; Hydrogen Chloride - During Combustion; Ammonia - During Combustion; Oxides of Nitrogen - During Combustion; Stability and Reactivity: Stable. Hazardous polymerization will not occur. ----------------------------------------------------------------------- 11 Toxicological Information ----------------------------------------------------------------------- Effects from Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Effects from Skin Contact: Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Effects from Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Effects from Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Sensitization Information: Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Carcinogenicity: No data available. Mutagenicity: No data available. Reproductive Effects: No data available. Component Based Information: No data available. Product Based Information: No data available. Skin Antiseptics (2.0% CHG) Page 6 of 7   ----------------------------------------------------------------------- ----------------------------------------------------------------------- 12 Ecological Information ----------------------------------------------------------------------- Environmental Data: Ecotoxicity Data: Not determined. Ecofate Data: Not determined. ----------------------------------------------------------------------- 13 Disposal Considerations ----------------------------------------------------------------------- Product as Sold: Incinerate in an industrial or commercial facility in the presence of a combustible material. Combustion products will include HCI. Facility must be capable of handling halogenated materials. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. Product Packaging: No data available. Special Instructions: Since regulations vary, consult applicable regulations or authorities before disposal. ----------------------------------------------------------------------- 14 Transport Information ----------------------------------------------------------------------- Transportation of Dangerous Goods --------------------------------- TDG Classification: Non-Regulated Material Special Information:: Contact 3M for more information. These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging, 3M policies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified for Canadian ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory requirements. International Dangerous Goods Classification -------------------------------------------- Skin Antiseptics (2.0% CHG) Page 7 of 7   ----------------------------------------------------------------------- ----------------------------------------------------------------------- 15 Regulatory Information ----------------------------------------------------------------------- WHMIS Classification: Exempt (Registered under Food and Drug Act). NOTE: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. Product Certifications: The product on this MSDS, or all its components, is included on the following countries' chemical inventories, as noted: AICS - Australian Inventory of Chemical Substances DSL - Domestic Substances List (Canada) CICS - Chinese Inventory of Chemical Substances EINECS - European Inventory of Existing Commercial Chemical Substances KECI - Korean Existing Chemicals Inventory TSCA - Toxic Substances Control Act (USA) ----------------------------------------------------------------------- 16 Other Information ----------------------------------------------------------------------- Reason for Reissue: The following Sections and topics have been updated or revised: Added French translation to MSDS The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. ---End---